Social security are not there to find you work, they are there to organise benefits payments. The only time I ever found a job through a job centre was by using the facilities of a jobseekers club to make loads of job applications.
If you do not have any work experience I would suggest studying through the open university to give you better qualifications or perhaps find a web development course which you could use to start your own business from home.
I have friends who work for the DSS and they get very frustrated by clients who expect to have jobs come to them, unfortunately the world does not work like that.